By E. Krause
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Chapter 2 Quadrupolar Nuclei in Solids Alexander J. 1 Introduction Basic Spin Properties Interaction with Radiofrequency Fields Experimental Methods Theory References 17 18 25 29 36 43 INTRODUCTION Nuclei with spin quantum number I 1 have an electric quadrupole moment that couples with the inhomogeneous internal electric ﬁelds existing in molecules and solids. Since this quadrupolar interaction is usually stronger than other interactions such as chemical shift and dipole–dipole couplings, it dominates the NMR spectra of quadrupolar nuclei in solid materials.
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Advances in Fluid Mechanics by E. Krause